An alternative explanation of back-relaxation in ionic polymer metal composites

Maurizio Porfiri

Department of Mechanical and Aerospace Engineering, Tandon School of Engineering Polytechnic Institute of New York University, Six MetroTech Center, Brooklyn, NY 11201, USA

Alessandro Leronni, Lorenzo Bardella

DICATAM, Faculty of Engineering, University of Brescia, Via Branze, 4325123, Brescia, Italy

Abstract

The phenomenon of back-relaxation in ionic polymer metal composites (IPMCs) has attracted the interest of the scientific community for two decades, but its physical origins largely remain elusive. Here, we propose an explanation of this phenomenon based on Maxwell stress. From first principles, we demonstrate that IPMC actuation is controlled by the nonlinear interplay between osmotic and electrostatic phenomena. While osmotic pressure tends to produce a rapid bending toward the anode, Maxwell stress generates a slow relaxation toward the cathode. The relative weight of these phenomena is determined by the applied voltage. At voltage levels comparable to the thermal voltage, IPMC actuation is dominated by osmotic effects. As the applied voltage is increased, Maxwell stress overcomes the osmotic pressure, leading to back-relaxation.

Author Keywords: Actuator; Electrochemistry; Maxwell stress; Poisson-Nernst-Planck